Water-soluble organotin compounds. Syntheses, structures and reactivity towards fluoride anion towards the fluoride anion

Massimiliano Arca
Investigation
;
Vito Lippolis
Supervision
;
2020

Abstract

Herein, we report the syntheses of the water-soluble organotin compounds [{Me2(H)N(CH2)3}2SnX2]Y2 (1, X = Cl, Y = ClO4; 2, X = F, Y = ClO4) and {Me2(H)N(CH2)3}2SnX4 (3, X = Cl; 4, X = F). The compounds were characterized by elemental analysis, electrospray mass spectrometry, 1H, 13C, 19F, and 119Sn NMR spectroscopy, and in the case of compounds 1, 3 and 4, by single-crystal X-ray diffraction analysis. The reaction of compound 2 with fluoride anions in water was investigated by NMR spectroscopy. DFT calculations accompany the experimental work.
2020
Inglese
2020
41
3925
3936
12
Esperti anonimi
internazionale
scientifica
tin; fluorides; cations; Lewis acids; structure elucidation; density functional calculations
Alashkar, Nour; Arca, Massimiliano; Alnasr, Hazem; Lutter, Michael; Lippolis, Vito; Jurkschat, Klaus
1.1 Articolo in rivista
info:eu-repo/semantics/article
1 Contributo su Rivista::1.1 Articolo in rivista
262
6
open
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