Supramolecular assemblies tailored by dipyridyl-1,2-4-thiadiazoles: influence of the building blocks in the predictability of the final network

Podda E.;Arca M.;Crespo Alonso M.;Isaia F.;Pintus A.;Lippolis V.;Aragoni M. C.
2020

Abstract

Coordinatively unsaturated dithiophosphato complex [Cd((MeO)2PS2)2] (1) was reacted with the bifunctional ligands 3,5-di-(4-pyridyl)-1,2,4-thiadiazole (L1) and 3,5-di-(3-pyridyl)-1,2,4-thiadiazole (L2) to give the helicoidal coordination polymer (1·L1)∞ and the paddle-wheel dimer (1·L2)2, both characterised by single-crystal X-ray diffraction. A comparison of the structures with the different supramolecular constructs obtained by reacting L1 and L2 with differently P-substituted dithiophosphoric NiII complexes allowed to evaluate the role of the metal ion for the predictable assembly of this class of coordination polymers.
2020
Inglese
32
4
267
275
9
Esperti anonimi
internazionale
scientifica
Coordination polymers (CPs); cadmium; dithiophosphates; XRD; supramolecular networks
Podda, E.; Arca, M.; Coles, S. J.; Crespo Alonso, M.; Isaia, F.; Pintus, A.; Lippolis, V.; Aragoni, M. C.
1.1 Articolo in rivista
info:eu-repo/semantics/article
1 Contributo su Rivista::1.1 Articolo in rivista
262
8
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