Titolo:  A facile strategy for new organic white LED hybrid devices: Design, features and engineering
Data di pubblicazione:  2016
Autori: 
Autori:  Luridiana, Alberto; Pretta, Gianluca; Chiriu, Daniele; Carbonaro, Carlo Maria; Corpino, Riccardo; Secci, Francesco; Frongia, Angelo; Stagi, Luigi; Ricci, Pier Carlo
Numero degli autori:  9
Lingua:  Inglese
Presenza coautori internazionali:  no
Rivista:  RSC ADVANCES
Volume:  6
Fascicolo:  26
Pagina iniziale:  22111
Pagina finale:  22120
Numero di pagine:  10
Digital Object Identifier (DOI):  http://dx.doi.org/10.1039/c6ra00999a
Codice identificativo Scopus:  2-s2.0-84959386518
Codice identificativo ISI:  WOS:000371535200092
URL:  http://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra00999a#!divAbstract
Parole Chiave:  Chemical Engineering (all); Chemistry (all)
Abstract:  A facile and ecofriendly strategy to design and engineer new organic white LEDs is tested. The hybrid system was implemented by combining a commercial blue LED, with emission at 405 nm, with a hybrid transparent organic film (polycarbonate, PMMA, PVC) containing two selected organic dyes. The emitting molecules, a home-designed push-pull based coumarin and DCM ([2-[2-[4-(dimethylamino)phenyl]ethenyl]-6-methyl-4H-pyran-4-ylidene]-propanedinitrile), were selected for their optical features and appropriately mixed to obtain white light, perceptible by the naked eye, through the metamerism effect. The proposed strategy shows the critical parameters to account for in the selection of organic dyes, bearing in mind the preservation of the dye emission properties from the solution to the solid state. To this purpose, the contributions of dynamic and static quenching effects were analyzed in detail, to single out the optimum concentrations to assure the compliance with the respective sphere of interaction and guarantee high optical performances. Different new hybrid white-emitting LEDs, with tunable color rendering index (from warm to cold CCT), high energy efficiency (quantum yield larger than 90%), and high photostability, were produced to prove the proposed strategy.
Tipologia: 1.1 Articolo in rivista

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